Waves and Modern Physics 203-SN3-RE • CEGEP, Montreal

Revision sheet: heat, temperature and heat transfer (203-SN3-RE)

The heat transfer chapter asks for few formulas and a lot of rigour about what they stand for: a temperature or a difference, a flow or a resistance, a sensible or a latent heat. It is almost always there, and not in the calculation, that marks are lost.

This sheet gathers the traps found in 203-SN3-RE tests, the tree that picks the law from the form of the question, two model write-ups and a composite wall solved step by step. It is written for CEGEP students in the Natural Science program (Sciences de la nature).

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The thread of the chapter

Temperature is a state, heat is a transfer: a body does not contain heat, it lets heat pass, from hot to cold, at a rate set by a resistance. Every trap in the chapter mixes up a state with a transfer, or a difference with a temperature.

This chapter is part of 203-SN3-RE, Waves and Modern Physics

The essentials

Temperature, thermal energy and heat

  • • TEMPERATURE is a state: it measures the average agitation of the particles. A difference of 11 °C is a difference of 11 K; an absolute temperature is T=θ+273.15T=\theta+273.15.
  • • HEAT QQ is energy in transit, exchanged because two bodies are not at the same temperature. A body does not “contain” heat.
  • • Sensible heat: Q=mc ΔTQ=mc\,\Delta T, the temperature changes. Latent heat: Q=mLQ=mL, the state changes and the temperature stays constant.
  • • Calorimetry in an insulated enclosure: ∑mici(Tf−Ti)+∑mjLj=0\sum m_{i}c_{i}(T_{f}-T_{i})+\sum m_{j}L_{j}=0, every term with its sign.
0 °C100 °C−20 °C100020003000energy received by 1 kg (kJ)Tmelting: 333 kJliquid waterboiling: 2260 kJvapourice
To scale for 11 kg: the boiling plateau (22602260 kJ) is almost seven times longer than the melting plateau (333333 kJ); on the plateaus, the energy received does not change the temperature.

On a heating curve, the plateaus are the moments when the energy received does not change the temperature: it breaks bonds. A calculation that crosses a plateau without an mL term is wrong.

The three modes and their laws

  • • Conduction (in a solid or a still fluid): Φ=kA ΔTe=ΔTR\Phi=\dfrac{kA\,\Delta T}{e}=\dfrac{\Delta T}{R}, with R=ekAR=\dfrac{e}{kA} in K/W. Successive layers: resistances in series, Rt=∑RiR_{t}=\sum R_{i}.
  • • Convection (a surface bathed by a fluid): Φ=hA (Ts−Tf)\Phi=hA\,(T_{s}-T_{f}). A cooling body: T(t)=Ta+(T0−Ta)e−ktT(t)=T_{a}+(T_{0}-T_{a})e^{-kt}.
  • • Radiation (even in a vacuum): P=εσAT4P=\varepsilon\sigma AT^{4}, net exchange P=εσA(T4−Te4)P=\varepsilon\sigma A\left(T^{4}-T_{e}^{4}\right), σ=5.67×10−8\sigma=5.67\times 10^{-8} W/(m²·K⁴).
  • • Wien's law: λmaxT=2.898×10−3\lambda_{max}T=2.898\times 10^{-3} m·K. Insulated cylinder: R=ln⁡(r2/r1)2πkLR=\dfrac{\ln(r_{2}/r_{1})}{2\pi kL}.
conductionΦ = ΔT / RconvectionΦ = hA (Ts − Tf)vacuumradiationP = εσAT⁴
In the bar, the energy passes from neighbour to neighbour without anything moving; in the pot, the fluid itself circulates; between the Sun and the Earth, only radiation crosses the vacuum.

The vocabulary of resistances is the same as in electricity: the temperature difference plays the role of the voltage, the flow that of the current.

The spectrum of thermal radiation

  • • A hot body emits a continuous spectrum whose peak lies at λmax=2.898×10−3T\lambda_{max}=\dfrac{2.898\times 10^{-3}}{T}: the hotter it is, the further this peak slides toward short wavelengths.
  • • The cooking element at 10731073 K emits mostly around 2.702.70 µm, in the infrared: its red glow is only the visible tail of its spectrum.
  • • The total power, the area under the curve, grows as T4T^{4}: from 293293 to 10731073 K, it is multiplied by 180180.
123456780.20.40.60.811.21373 K: peak at 2.11 µm1073 K: peak at 2.70 µmvisibleλ (µm)emitted intensity
The hotter curve is higher at every wavelength and its peak moves back toward the visible; at 10731073 K, the peak stays at 2.702.70 µm, far into the infrared.

The mistakes that cost marks

These are the errors I correct most often in session. Each one costs marks on a paper, even when the reasoning behind it is right.

1. Putting degrees Celsius in a law with T to the fourth power

the whole question, and a result three times too small

What not to write

“Element at 800800 °C: P=0.90×σ×0.018×8004=376P=0.90\times\sigma\times 0.018\times 800^{4}=376 W.”

What to write

“T=800+273=1073T=800+273=1073 K, so P=0.90×σ×0.018×10734=1.22×103P=0.90\times\sigma\times 0.018\times 1073^{4}=1.22\times 10^{3} W.”

376 W800⁴wrong1218 W1073⁴rightelement: ε = 0.90, A = 0.018 m²
In kelvins, the element radiates 1.221.22 kW (green); with the number 800800 taken as an absolute temperature, 376376 W (red): the fourth power multiplies the error by 3.23.2.

Why: The Stefan-Boltzmann law is written for the ABSOLUTE temperature. For a difference ΔT\Delta T (Fourier, Newton, mcΔTmc\Delta T), Celsius and kelvins give the same number; for T4T^{4}, never.

2. Calculating the flow in each layer of a wall with the total difference

the whole question, and a flow twenty times too large

What not to write

“Brick: 300.0139=2160\dfrac{30}{0.0139}=2160 W; insulation: 300.25=120\dfrac{30}{0.25}=120 W; total flow 22802280 W.”

What to write

“Layers crossed one after the other: Rt=0.0139+0.25=0.264R_{t}=0.0139+0.25=0.264 K/W, and Φ=300.264=114\Phi=\dfrac{30}{0.264}=114 W, the same in each layer.”

brickdrop 1.6 Kinsulationdrop 28.4 Kin series: Φ = 30 / 0.264 = 114 Wwrong: 2160 + 120 = 2280 Wwallwindowside by side:the flows add
In series, a single flow crosses brick then insulation, and it is the 3030 K difference that is divided. Flows add only for walls side by side, like a wall and its window.

Why: In series, it is the FLOW that is shared and the temperature difference that is divided among the layers. Adding flows only makes sense for walls side by side, in parallel, like a wall and a window.

3. Forgetting latent heat when ice melts

the whole question, with an absurd final temperature

What not to write

“5050 g of ice at 00 °C in 250250 g of water at 2525 °C: T=0.25×25+0.05×00.30=20.8T=\dfrac{0.25\times 25+0.05\times 0}{0.30}=20.8 °C.”

What to write

“0.25×4186×(25−T)=0.05×3.33×105+0.05×4186×T0.25\times 4186\times(25-T)=0.05\times 3.33\times 10^{5}+0.05\times 4186\times T, so T=7.6T=7.6 °C.”

melt the ice: 16.7 kJleft: 9.5 kJwhat 250 g of water at 25 °C gives up down to 0 °C: 26.2 kJright: the 9.5 kJ warm 300 g of water, T = 7.6 °Cwrong: 20.8 °C, melting forgotten
Melting uses 16.716.7 of the 26.226.2 kJ the water can give up: only 9.59.5 remain to warm the 300300 g, hence 7.67.6 °C (green) and not 20.820.8 (red).

Why: Melting the ice costs 16.716.7 kJ before it is even warmed, more than half of what the water can give up on its way back to 00 °C. Always check first whether all the ice melts.

4. Letting the temperature decay instead of the difference

the whole question, and a model that tends toward 0 °C

What not to write

“Coffee at 9090 °C, k=0.05k=0.05 min⁻¹: after 3030 min, T=90 e−1.5=20.1T=90\,e^{-1.5}=20.1 °C.”

What to write

“It is the difference from the room that decays: T=20+70 e−1.5=35.6T=20+70\,e^{-1.5}=35.6 °C.”

10203040506020406080100right: toward 20 °Cwrong: toward 0 °CT (°C) versus t (min)
The right curve settles onto the 20 °C line; the wrong curve, dashed, crosses the room temperature and keeps going toward 0 °C, which no coffee ever does.

Why: Newton's law acts on T−TaT-T_{a}: the body tends toward the ambient temperature, not toward zero. The wrong model predicts a coffee that would end up colder than the room.

5. Leaving the thickness in centimetres in Fourier's law

2 marks, and a result a hundred times too small

What not to write

“Cooler: Φ=0.033×0.80×303=0.26\Phi=\dfrac{0.033\times 0.80\times 30}{3}=0.26 W.”

What to write

“e=3.0e=3.0 cm =0.030=0.030 m: Φ=0.033×0.80×300.030=26.4\Phi=\dfrac{0.033\times 0.80\times 30}{0.030}=26.4 W.”

Why: The conductivity is in W/(m·K): the thickness must be in metres, the area in square metres. A cooler that let in only a quarter of a watt would keep its ice for months.

6. Forgetting what the body receives from its surroundings

3 marks, and a person who would freeze to death within an hour

What not to write

“The human body (1.81.8 m², ε=0.97\varepsilon=0.97, skin at 306306 K) loses εσAT4=868\varepsilon\sigma AT^{4}=868 W by radiation.”

What to write

“In a room at 293293 K, it loses εσA(3064−2934)=138\varepsilon\sigma A\left(306^{4}-293^{4}\right)=138 W: it receives almost as much as it emits.”

emitted: 868 Wreceived: 730 Wnet: 138 Wskin at 306 K, walls at 293 Kwrong: 868 W lost
The skin emits 868868 W, but the walls send back 730730: only the net exchange, 138138 W (green), counts in the balance.

Why: Every body radiates AND absorbs. When the two temperatures are close, the net exchange is a small difference between two large numbers, and it alone counts in a balance.

7. Believing that doubling the insulation on a pipe halves the flow

2 marks on an interpretation question

What not to write

“The insulation goes from 2.52.5 to 5.05.0 cm thick: the heat flow lost is divided by two.”

What to write

“R=ln⁡(r2/r1)2πkLR=\dfrac{\ln(r_{2}/r_{1})}{2\pi kL}: the flow is divided by only ln⁡(6.1/1.1)ln⁡(3.6/1.1)=1.44\dfrac{\ln(6.1/1.1)}{\ln(3.6/1.1)}=1.44.”

1234560.511.522.55.0 cm: × 1.44wrong: × 22.5 cminsulation thickness (cm), pipe with r₁ = 1.1 cmR / R(2.5 cm)
Each centimetre added far from the axis offers more surface and resists less: doubling the sleeve multiplies RR by 1.441.44 (green), not by 22 as for a flat wall (red).

Why: The added layer is farther from the axis, its surface is larger: it resists less than the first one. Proportionality to the thickness holds only for a flat wall.

Which method to choose

Which law, from the form of the question

What the question gives to describe the transfer

hot coffeestopper: conduction,Φ = kAΔT / esilvered walls: radiation,low εvacuum: no conductionand no convection
A single object calls on several branches: conduction through the stopper, radiation between the silvered walls, and the vacuum that removes conduction and convection.
  • If a thickness, a conductivity k, a solid material → conduction: Φ=kAΔTe\Phi=\dfrac{kA\Delta T}{e}, resistances in series for several layers

    Example: 0.033×0.80×300.030=26.4\dfrac{0.033\times 0.80\times 30}{0.030}=26.4 W

  • If a coefficient h, a fluid in contact with a surface → convection: Φ=hAΔT\Phi=hA\Delta T

    Example: 25×0.054×40=5425\times 0.054\times 40=54 W

  • If an emissivity, a high temperature, a vacuum → radiation: εσA(T4−Te4)\varepsilon\sigma A\left(T^{4}-T_{e}^{4}\right), in kelvins

    Example: 0.97σ×1.8×(3064−2934)=1380.97\sigma\times 1.8\times(306^{4}-293^{4})=138 W

  • If a temperature that changes in time toward that of the surroundings → Newton's law: T=Ta+(T0−Ta)e−ktT=T_{a}+(T_{0}-T_{a})e^{-kt}

    Example: 20+70e−1.5=35.620+70e^{-1.5}=35.6 °C

  • If ice, steam, a plateau → latent heat Q=mLQ=mL before any mcΔTmc\Delta T

    Example: 0.050×3.33×105=16.70.050\times 3.33\times 10^{5}=16.7 kJ

One problem often combines two branches: the cooler is a conduction that feeds a melting, the vacuum flask a conduction through the stopper plus a radiation between the walls.

How the answer is expected to be written

A marker ticks steps. Here they are in order, with the concluding sentence expected word for word.

A calorimetry problem with ice, written for the marker

When to use it: The question mixes ice (or steam) with a liquid and asks for a final temperature.

  1. 1 Calculate the energy the hot body can give up on its way down to 00 °C, and the energy needed to bring the ice to 00 °C and then melt it completely.
  2. 2 Compare: if the hot body can supply more than is needed, all the ice melts and the final temperature is above 0 °C; otherwise the final state is a mixture at 0 °C.
  3. 3 Write the complete balance, every term with its sign: mwcw(Tf−Tw)+miceLf+micecw(Tf−0)=0m_{w}c_{w}(T_{f}-T_{w})+m_{ice}L_{f}+m_{ice}c_{w}(T_{f}-0)=0.
  4. 4 Solve, then check that TfT_{f} lies between 00 °C and the initial temperature of the hot body.

Concluding sentence

“The water can give up 26.226.2 kJ on its way back to 00 °C, melting requires only 16.716.7: all the ice melts, and the balance gives Tf=7.6T_{f}=7.6 °C.”

The trap: Writing the balance straight away while assuming all the ice melts, without checking: if the water is not warm enough, you get a negative temperature, a sign that ice remains.

Marking: Typically 1 mark for the comparison of the energies, 2 for the complete balance, 1 for the solution, 1 for the check.

Finding the constant k in Newton's law

When to use it: The question gives two temperature measurements at two instants and the ambient temperature.

  1. 1 Write the two DIFFERENCES from the ambient temperature, never the temperatures themselves.
  2. 2 Form their ratio: T2−TaT1−Ta=e−k(t2−t1)\dfrac{T_{2}-T_{a}}{T_{1}-T_{a}}=e^{-k(t_{2}-t_{1})}.
  3. 3 Isolate k=1t2−t1ln⁡T1−TaT2−Tak=\dfrac{1}{t_{2}-t_{1}}\ln\dfrac{T_{1}-T_{a}}{T_{2}-T_{a}}, with its unit (s⁻¹, min⁻¹ or h⁻¹).
  4. 4 Reuse the same ratio to go back or forward in time.

Concluding sentence

“Between the two measurements, the difference goes from 11.011.0 to 8.58.5 K in 22 h, so k=12ln⁡11.08.5=0.129k=\dfrac{1}{2}\ln\dfrac{11.0}{8.5}=0.129 h⁻¹.”

The trap: Writing the ratio of the temperatures 29.0 over 26.5 instead of the ratio of the differences: you get a constant almost three times too small.

Check before you hand in

Five minutes of checking recover more marks than one more problem started in a hurry.

The typical problem, taken apart

A three-layer wall: flow and interface temperature

A wall of 1010 m² is made, from inside to outside, of 1.51.5 cm of plaster (k=0.25k=0.25 W/(m·K)), 1010 cm of mineral wool (k=0.040k=0.040) and 2.02.0 cm of wood (k=0.12k=0.12). It is 2020 °C inside and −10-10 °C outside.

Calculate the heat flow, then the temperature between the wool and the wood.

mineral wool10 cmk = 0.040plaster: 1.5 cmk = 0.25wood: 2.0 cmk = 0.12inside20 °Coutside−10 °CΦ, wall of 10 m²k in W/(m·K)
Three layers crossed one after the other by the same flow, from 2020 °C to −10-10 °C: thicknesses to scale and the conductivity of each, nothing calculated.

Step 1

Resistances: Rp=0.0150.25×10=0.0060R_{p}=\dfrac{0.015}{0.25\times 10}=0.0060; Rm=0.100.040×10=0.25R_{m}=\dfrac{0.10}{0.040\times 10}=0.25; Rw=0.0200.12×10=0.0167R_{w}=\dfrac{0.020}{0.12\times 10}=0.0167 K/W.

Why

Convert all thicknesses to metres before dividing: the factor-of-a-hundred error is eliminated on the very first line.

Step 2

In series: Rt=0.0060+0.25+0.0167=0.273R_{t}=0.0060+0.25+0.0167=0.273 K/W.

Why

The three layers are crossed one after the other by the same heat: it is the resistances that add up, not the flows.

Step 3

Φ=20−(−10)0.273=110\Phi=\dfrac{20-(-10)}{0.273}=110 W.

Why

The difference is 30 K; the double sign is the second trap of the question.

Step 4

Drop in the plaster: 110×0.0060=0.66110\times 0.0060=0.66 K; in the wool: 110×0.25=27.5110\times 0.25=27.5 K. Wool-wood interface: 20−0.66−27.5=−8.220-0.66-27.5=-8.2 °C.

2468101214−10−5510152025wool: 27.5 Kplaster: 0.66 Kinterface: −8.2 °Cwood: 1.8 Kposition in the wall (cm)T (°C)

Why

Each layer uses up a difference ΦR\Phi R, as a resistor uses up a voltage: we step down layer by layer from the inside.

Step 5

Check: −8.2−(−10)=1.8-8.2-(-10)=1.8 K remain for the wood, and 110×0.0167=1.8110\times 0.0167=1.8 K.

Why

The sum of the drops gives back the total difference: the check costs one line and confirms the whole calculation.

The conclusion, written out

“The wall loses 110110 W. The wool carries 9292 % of the resistance: the wool-wood interface is already at −8.2-8.2 °C, less than two degrees from the outside.”

The classic mistake on this problem: Calculating a flow per layer with the total difference of 30 K and adding them, which gives several kilowatts for an insulated wall.

Learn by heart

  • • Temperature: a state. Heat: a transfer, from hot to cold.
  • • Q=mcΔTQ=mc\Delta T without a change of state; Q=mLQ=mL during a plateau, at constant temperature.
  • • Fourier: Φ=ΔTR\Phi=\dfrac{\Delta T}{R} with R=ekAR=\dfrac{e}{kA}, thickness in metres; in series, Rt=∑RiR_{t}=\sum R_{i}.
  • • Newton: it is the difference T−TaT-T_{a} that decays as e−kte^{-kt}.
  • • Stefan-Boltzmann: P=εσAT4P=\varepsilon\sigma AT^{4}, TT in kelvins; net balance εσA(T4−Te4)\varepsilon\sigma A(T^{4}-T_{e}^{4}).
  • • Wien: λmaxT=2.898×10−3\lambda_{max}T=2.898\times 10^{-3} m·K.
  • • Pipe: R=ln⁡(r2/r1)2πkLR=\dfrac{\ln(r_{2}/r_{1})}{2\pi kL}, doubling the insulation does not halve the flow.

Frequently asked questions

What is the difference between heat and temperature?

Temperature describes the state of a body, the average agitation of its particles. Heat is energy that passes from one body to another because their temperatures differ. A body has a thermal energy and a temperature, but never a quantity of heat: heat exists only during the transfer.

Why does the temperature stay constant while ice melts?

Because the energy received goes into breaking the bonds that hold the molecules in the crystal, not into increasing their agitation. As long as some ice remains, the mixture of water and ice stays at zero degrees Celsius. This energy is calculated with the latent heat of fusion, multiplied by the mass that melts.

How do you calculate the heat flow through a wall of several layers?

You calculate the thermal resistance of each layer, the thickness divided by the product of the conductivity and the area, then add these resistances because the heat crosses the layers one after the other. The flow equals the total temperature difference divided by the total resistance, and it is the same in every layer.

Should temperatures be in kelvins in heat transfer calculations?

For a temperature difference, in Fourier's law, Newton's law or the calculation of sensible heat, degrees Celsius and kelvins give the same number. For radiation, where the temperature is raised to the fourth power, the absolute temperature in kelvins is mandatory.

Practise it

Corrected exercises: Heat, temperature and heat transfer, 203-SN3-RE

A method is proved on a paper, not on a sheet. The set for the same chapter takes each of these traps into a problem, with the solution written out step by step.

  • 15 corrected exercises
  • 150 points
  • 225 minutes
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© Ahmed Squalli Houssaini. Revision sheet published at www.letuteurscientifique.ca/en/fiches/cegep-phys3-heat-transfer. Free for personal and classroom use; republishing it elsewhere requires written permission (legal notice).

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